An unusual hydrogen migration/C-H activation reaction with group 3 metals.

نویسندگان

  • Bryan N Williams
  • Diego Benitez
  • Kevin L Miller
  • Ekaterina Tkatchouk
  • William A Goddard
  • Paula L Diaconescu
چکیده

A novel hydrogen migration from the phenyl ring to the pyridine ring of an yttrium pyridyl complex supported by a 1,1'-ferrocene diamide ligand is reported. Density functional theory calculations were instrumental in probing the mechanism for this transformation.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 133 13  شماره 

صفحات  -

تاریخ انتشار 2011